This paper introduced the concept of chiral polymer, then reviewed the application of natural chiral polymer and synthesis chiral polymer on chiral separation. 在回顾手性高分子化合物概念的基础上,综述了天然手性高分子和合成手性高分子在手性物质分离中的应用情况。
Recent Development In Asymmetric Catalysis Using Chiral Polymer 手性聚合物在不对称催化反应中的新进展
Preparation of Novel Chiral Polymer Stationary Phase 新型高分子手性固定相的制备
The mobile phase conditions ( pH, methanol content, buffer concentration, etc.) could significantly influence the chiral separation ability of metal-complexing imprinted ( polymer). 用它作为色谱固定相,系统考察了流动相的pH、甲醇含量以及缓冲溶液的浓度对其手性分离能力的影响。
A Novel Chiral Selector in Capillary Electrophoresis& β Cyclodextrin Polymer 用于毛细管电泳手性分离的一种新的手性选择剂&β-环糊精聚合物
Synthesis and Properties of Chiral Conjugated Polymer Incorporating ( R)-and ( S)-1,1 ′-Binaphthyl and Oxadiazole Units 含(R)或(S)-1,1′-联萘和恶二唑单元的手性高分子合成与性质研究
The separation conditions were optimized by changing the types of chiral selector, the concentration of CD polymer, and pH of background electrolyte. 考察了不同手性选择剂及其浓度、背景电解质的pH等操作条件对分离的影响。
Retention Behaviours of PAHs on Liquid Crystalline Polymer Stationary Phases Novel chiral polymer stationary phases were prepared by free-radical polymerization of 3 on silica gel. 多环芳烃在高分子液晶柱上的保留行为3在丙烯酰化硅胶表面发生自由基聚合反应,得到用于高效液相色谱柱的新型高分子手性固定相。
The Enantiomeric Separation of Rosiglitazone and Fenfluramine Chiral Drugs with Water-soluble β-CD Polymer in Capillary Electrophoresis 水溶性β-CD聚合物在毛细管电泳中分离手性药物罗格列酮和芬氟拉明
The effect of temperature on the chiral separation of the molecular imprinting polymer was investigated and the thermodynamic parameters were calculated. 考察了温度对分子烙印固定相手性分离的影响,计算了手性分离过程中的热力学参数。
Study on fabrication of chiral polymer cholesteric liquid crystal-E film and its polarization 手性E型胆甾相液晶薄膜的制备与偏振特性研究
Studies on structure of oriented film of a chiral side chain liquid crystalline polymer 手征性侧链液晶高分子取向结构的研究
A series of chiral molecular imprinted polymer were synthesized from ( R)-acryloyl-1-naphthylethylamine ( 1, chiral functional monomer) which was obtained from aromatic amine and acrylamide. 以手性芳胺为母体,丙烯酰氯为酰化试剂,合成了新型手性功能单体(1)。用1合成了一系列手性分子印迹聚合物。
This paper analyzes the important positions of stealth materials in stealth technology, and introduces the study of application status of chiral material, nano metrical, electro-conduction polymer, polycrystal femur materials in detail. 分析了隐身材料在隐身技术中的重要地位,较详细地介绍了手性材料、纳米材料、导电高聚物材料、多晶铁纤维材料的研究和应用现状。
Mixture was made of chiral additive and liquid crystal polymer, which properties were studied. Whether the mixture has ferroelectricity has been discussed, which would establish some bases for the research and application of the liquid crystal display materials and nonlinear optical materials in future. 将液晶手性添加剂和液晶聚合物共混,并研究了共混物的性能,探讨了共混型丙烯酸酯类液晶聚合物的铁电性能,为将来的液晶显示材料及非线形光学材料的研究及应用奠定了基础。
Studies on the Synthesis and Asymmetric Catalytic Properties of the Chiral Polymer 手性聚合物的合成及其不对称催化性能研究
Directly to the current isosorbide as a chiral agent to isosorbide synthetic element with the liquid crystal monomer and the polymer has not been reported. 目前直接以异山梨醇作为手性剂来合成含异山梨醇基元的液晶单体及其聚合物报道很少。
Simultaneously it is also the important way to synthesize chiral organic compounds. Therefore, cyanation has a considerable applications in organic chemicals, medicines, pesticides, dyestuff, pigments, crystal materials and polymer materials. 同时氰化反应也是合成手性有机化合物的重要途径,因此在有机化学工业、医药、农药、染料、颜料、液晶材料、高分子材料等行业中有着十分重要的应用。
The unusual optical, magnetic, electric and mechanical properties of chiral materials make them a wide range of promising applications in the fields of biology, medicine, polymer materials, nanoelectromechanical systems ( NEMS) and stealth materials. 它一般具有独特的光、电、磁以及力学等性能,在生物、医学、高分子材料、纳米机电系统和隐身材料等领域具有良好的应用前景。
Rapid chiral separations were achieved on it by combining high flow rate with gradient elution. A cinchonine imprinted monolithic polymer was directly prepared in a fused capillary column by in-situ polymerization. 借助于提高流速和使用梯度洗脱在其上实现了快速手性分离。采用原位聚合法直接在毛细管柱中合成出具有大孔结构的整体毛细管分子印迹柱。
The dramatic morphology change of this chiral polymer driven by light was observed in TEM and SEM images. 手性聚合物在光驱动下产生的显著形态变化也通过TEM和SEM观察。